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Derived absolute rate constants for additions of ambiphilic carbenes to alkenes

✍ Scribed by Robert A. Moss; Chuan-Sheng Ge; Joanna Włostowska; Eun G. Jang; Elizabeth A. Jefferson; Hong Fan

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
267 KB
Volume
36
Category
Article
ISSN
0040-4039

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Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants