✦ LIBER ✦

Absolute rate constants for the additions of halophenylcarbenes to alkenes: a reactivity-selectivity relation

✍ Scribed by D.Phillip Cox; Ian R. Gould; Nigel P. Hacker; Robert A. Moss; Nicholas J. Turro

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 214 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87856-9

No coin nor oath required. For personal study only.

✦ Synopsis

The absolute rate constants determined for the additions of FCPh, ClCPh, and BrCPh to Me2C=CMez, MepC=CHMe, trans-MeCH=CHEt, and n-BuCH=CH2 appear to follow a reactivity/selectivity pattern of the "normal" (inverse) type.

📜 SIMILAR VOLUMES

Derived absolute rate constants for addi

Derived absolute rate constants for additions of ambiphilic carbenes to alkenes

✍ Robert A. Moss; Chuan-Sheng Ge; Joanna Włostowska; Eun G. Jang; Elizabeth A. Jef 📂 Article 📅 1995 🏛 Elsevier Science 🌐 French ⚖ 267 KB

Absolute rate Constants for the Addition

Absolute rate Constants for the Addition of Malonyl Radicals to Alkenes in Solution

✍ Matthias Weber; Hanns Fischer 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 632 KB

Absolute rate constants for the addition

Absolute rate constants for the addition of hydroxymethyl radicals to alkenes in methanol solution

✍ J. Q. Wu; H. Fischer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants

Linear Reactivity-Selectivity Correlatio

Linear Reactivity-Selectivity Correlations in Additions of Diarylcarbenium Ions to Alkenes; a Rebuttal of the Reactivity-Selectivity Principle

✍ Prof. Dr. Herbert Mayr; Dipl.-Chem. Reinhard Schneider; Ute Grabis 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 223 KB 👁 2 views

Absolute Rate Constants for the Addition

Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical to Alkenes in Solution

✍ Bernhard Knühl; Sylvain Marque; Hanns Fischer 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 114 KB 👁 2 views

Direct Determination of Rate Constants f

Direct Determination of Rate Constants for the Addition of Carbenium Ions to Alkenes

✍ Dipl.-Chem. Reinhard Schneider; Ute Grabis; Prof. Dr. Herbert Mayr 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB 👁 2 views