l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
A new Schiff base copper (II) complex: bis[N-(4-hydroxysalicylidene)-N′,N′-diethylethylenediamine-κ2N,O]bis[(oxalato-κ2O,O′)copper(II)] dihydrate
✍ Scribed by Xu, Guang-Jun ;Yan, Shi-Ping ;Liao, Dai-Zheng ;Jiang, Zong-Hui ;Cheng, Peng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 398 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
A new Schiff base copper (II) complex: bis
📜 SIMILAR VOLUMES
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
The title compound, [Cu(C 2 O 4 ) 2 (C 6 H 9 N 2 ) 2 ], crystallizes in the space group P2 1 /c, with the Cu atom located at a centre of symmetry. It is a neutral coordination complex in which the metal exhibits a tetragonally elongated octahedral trans-CuO 4 N 2 coordination environment. Extensive
l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)
In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.