A kinetic isotope effect in the tricyanovinylation of dimethylaniline
โ Scribed by P.G. Farrell; J. Newton
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 165 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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RECENT studies of secondary kinetic isotope effects have focussed on reactions which involve bond making and breaking at or near the site of isotopic substitution. We have now observed a mass effect in a purely conformational change: the racemization of diketones I and II. In connection with our wor
Both the maximum we.Locity and the Michae.U canotati od Xhe oxy,qena.tion od N,N-dimeXhyfaniLLne with the pig k!iveh nichodomal FAV-contain&y monooxggenane (EC J.14.13.b) to N,N-dimtihyLanXine N-oxide appewt 1.7 Qoldn yteaakt in aqueoti bu6de.4 ooLution 06 pff 7.4 than thobe i.n deutetium oxide budd