Deuterium kinetic isotope effect on quaternization of N,N-dimethylaniline
✍ Scribed by J. Rudziński; N. Tadros; P. Paneth
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 274 KB
- Volume
- 321
- Category
- Article
- ISSN
- 0022-2860
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Lignin peroxidase catalyses the oxidative N-demethylation of ring-substituted N,N-dimethylanilines by an electrontransfer mechanism whereby an anilinium radical cation is formed which is then deprotonated by the enzyme. Information on the nature of the basic centre which deprotonates the radical cat
A blue-shxft of the "'hidden band" of N,Ndimethylanike is observed for the first time, by Iowering the tempesattrz. me linear dlchroism is spetic for this effect, only the second transition is shifted. This behavkxu is amsisteilt with the Rydbag character of this transition, but we have no absolute