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The kinetic isotope effect in the photochlorination of methane

✍ Scribed by K.B. Wiberg; E.L. Motell

Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
932 KB
Volume
19
Category
Article
ISSN
0040-4020

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## Abstract The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gas‐phase photolysis of H~2~O~2~ with ultraviolet light produced by a high‐pressure mer