The thermal decomposition of deuterated ethyl chloride CHzDCHzCl was studied in a static system in the pressure range of 0.1-26 torr, and the Arrhenius expression for the overall decomposition at the high-pressure limit and in the temperature range of 670-1100 K was found to be k , = 1013.33\*0.10 e
Kinetic isotope effects in the photochlorination of gaseous ethyl chloride-2-d1
โ Scribed by Jan Niedzielski; T. Yano; K.-H. Jung; E. Tschuikow-Roux
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 759 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0047-2670
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## Abstract Firstโorder rate constants for formation of cyclohexanone and 2โcyclohexenโ1โol from 1,2โepoxycyclohexane and 1,2โepoxycyclohexaneโ3,3,6,6โ__d__~4~ have been determined over the temperature range of 677โ746ยฐK. The observed kinetic isotope effects are used in an attempt to determine the