The abstraction of hydrogen/deuterium from CH3CH2C1, CH,CHDCl, and CH,CD,Cl by photochemically generated ground-state chlorine atoms has been investigated over the temperature range of 8-94ยฐC using methane as a competitor. Rate constant data for the following reactions have been obtained: (1) CH,C&C
Secondary kinetic isotope effects in hydrogen and deuterium abstraction by chlorine atoms from the chloromethyl group in gaseous ethyl chlorides: effects of isotopic substitution in the adjacent methyl group
โ Scribed by E. Tschuikow-Roux; Jan Niedzielski
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 743 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0047-2670
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