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Carbon kinetic isotope effect in the oxidation of methane by hydroxyl

โœ Scribed by Fleet Rust; C. M. Stevens

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
319 KB
Volume
12
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

Abstract

The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gasโ€phase photolysis of H~2~O~2~ with ultraviolet light produced by a highโ€pressure mercury arc lamp. Implications for the tropospheric cycle of CH~4~ are considered briefly.

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