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Kinetics of the reactions of cyclopropane derivatives. IV. Kinetic isotope effect in the isomerisation of cyclopropylamine

✍ Scribed by D. A. Luckraft; P. J. Robinson

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
119 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The high‐pressure isotopic rate ratio k~H~/k~D~ for isomerisation of cyclopropylamine and cyclopropylamine‐N‐d~2~ is 1.06 at 649–678 K, supporting a mechanism which does not involve migration of hydrogen from the amine group in the rate‐determining step.

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