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π-Facial Diastereoselectivity in the [4+2] Cycloaddition of Singlet Oxygen as a Mechanistic Probe

✍ Scribed by Adam, Waldemar; Prein, Michael

Book ID
118120557
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
365 KB
Volume
29
Category
Article
ISSN
0001-4842

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Substituent effects in the diastereosele
Substituent effects in the diastereoselective [4+2] cycloaddition of chiral naphthalene derivatives with singlet oxygen
✍ Waldemar Adam; Michael Prein 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 382 KB

A bsfracf: From 1 -bromo4-methylnaphthalene eight chiml derivatives 1 with a variety of functional groups at the stereo&e& center were prepcued, which with singlet oxysen led to the corresponding endoperoxides 2 in substituenr-dependent n7facial selectivity of stereoelectronic origin.