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π-Facial selectivity of the singlet oxygen [4+2] cycloaddition to chiral naphthalene derivatives: The directing effect of carbon-containing substituents

✍ Scribed by Waldemar Adam; Michael Prein


Book ID
107857677
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
581 KB
Volume
51
Category
Article
ISSN
0040-4020

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Substituent effects in the diastereosele
✍ Waldemar Adam; Michael Prein 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 382 KB

A bsfracf: From 1 -bromo4-methylnaphthalene eight chiml derivatives 1 with a variety of functional groups at the stereo&e& center were prepcued, which with singlet oxysen led to the corresponding endoperoxides 2 in substituenr-dependent n7facial selectivity of stereoelectronic origin.