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Diastereoselective [4 + 2] cycloaddition of singlet oxygen in the photooxygenation of chiral naphthyl alcohols: evidence for a hydroxy group-directing effect

✍ Scribed by Adam, Waldemar; Prein, Michael


Book ID
126965653
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
210 KB
Volume
115
Category
Article
ISSN
0002-7863

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Substituent effects in the diastereosele
✍ Waldemar Adam; Michael Prein πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 382 KB

A bsfracf: From 1 -bromo4-methylnaphthalene eight chiml derivatives 1 with a variety of functional groups at the stereo&e& center were prepcued, which with singlet oxysen led to the corresponding endoperoxides 2 in substituenr-dependent n7facial selectivity of stereoelectronic origin.