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Diastereoselective Photooxygenation of Chiral Naphthyl Alcohols: The Hydroxy Group Directing Effect in Singlet Oxygen [4+2] Cycloaddition to Arenes

✍ Scribed by Adam, Waldemar; Peters, Eva Maria; Peters, Karl; Prein, Michael; von Schnering, Hans Georg


Book ID
121875770
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
537 KB
Volume
117
Category
Article
ISSN
0002-7863

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Substituent effects in the diastereosele
✍ Waldemar Adam; Michael Prein πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 382 KB

A bsfracf: From 1 -bromo4-methylnaphthalene eight chiml derivatives 1 with a variety of functional groups at the stereo&e& center were prepcued, which with singlet oxysen led to the corresponding endoperoxides 2 in substituenr-dependent n7facial selectivity of stereoelectronic origin.