Substituent effects in the diastereoselective [4+2] cycloaddition of chiral naphthalene derivatives with singlet oxygen

✍ Scribed by Waldemar Adam; Michael Prein

• Book ID: 104214564
• Publisher: Elsevier Science
• Year: 1994
• Tongue: French
• Weight: 382 KB
• Volume: 35
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)73346-6

✦ Synopsis

A bsfracf: From 1 -bromo4-methylnaphthalene eight chiml derivatives 1 with a variety of functional groups at the stereo&e& center were prepcued, which with singlet oxysen led to the corresponding endoperoxides 2 in substituenr-dependent n7facial selectivity of stereoelectronic origin.