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Substituent Effects in the Highly Regioselective and Diastereoselective Ene Reaction of Singlet Oxygen with Chiral Cyclohexadienes

✍ Scribed by Linker, Torsten; Froehlich, Lothar


Book ID
126268550
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
512 KB
Volume
117
Category
Article
ISSN
0002-7863

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Substituent effects in the diastereosele
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A bsfracf: From 1 -bromo4-methylnaphthalene eight chiml derivatives 1 with a variety of functional groups at the stereo&e& center were prepcued, which with singlet oxysen led to the corresponding endoperoxides 2 in substituenr-dependent n7facial selectivity of stereoelectronic origin.