✦ LIBER ✦

μ-Oxalato-κ2O1,O2:κ2O1′,O2′-bis[(η5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-κO)rhodium(III)]

✍ Scribed by Govindaswamy, Padavattan ;Süss-Fink, Georg ;Therrien, Bruno

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 621 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807031790

No coin nor oath required. For personal study only.

✦ Synopsis

In the title dinuclear rhodium complex, [(-

the terminal trifluoromethanesulfonate ligands adopt a trans configuration with respect to each other and the RhÁ Á ÁRh distances range from 5.5157 (8) to 5.5389 (6) A ˚. There are two and a half molecules within the asymmetric unit, one of the molecules lying on an inversion centre. Interestingly, in one molecule, the S-O bond of a coordinated O atom is shorter than the two S-O bonds of the noncoordinated O atoms, and the corresponding Rh-O distance is significantly longer than the other M-O distances.

📜 SIMILAR VOLUMES

(Bipyridyl-κ2N,N′)bis(η5-pentamethylcycl

(Bipyridyl-κ2N,N′)bis(η5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-κO)cerium(III)

✍ Kazhdan, Daniel ;Chomitz, Wayne A. ;Harman, William H. ;Hoette, Trisha M. ;Park, 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 481 KB

The title compound, [Ce(CF 3 SO 3 )(C 10 H 15 ) 2 (C 10 H 8 N 2 )], crystallizes as a bent metallocene with an inner-sphere trifluoromethanesulfonate ligand [Cg1-Ce-Cg2 = 138.91 (1) A ˚; Cg1 and Cg2 are the centroids of the cyclopentadienyl rings]. The pentamethylcyclopentadienyl rings have a slight

μ-Oxalato-κ2O1,O2:κ2O1′,O2′-bis[(3,5-di

μ-Oxalato-κ2O1,O2:κ2O1′,O2′-bis[(3,5-dicarboxybenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N′)copper(II)]

✍ Qin, Chao 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 182 KB

)(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]

catena-Poly[[bis(3-pyridylmethanol-κN)c

catena-Poly[[bis(3-pyridylmethanol-κN)copper(II)]-μ-oxalato-1κ2O1,O2:2κ2O1′,O2′]

✍ Jašková, Jana ;Mikloš, Dušan ;Segľa, Peter ;Sillanpää, Reijo ;Moncol, Jan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 102 KB

In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o

μ-Oxalato-1κ2O,O′:2κ2O′′,O′′′-bis(chlor

μ-Oxalato-1κ2O,O′:2κ2O′′,O′′′-bis(chloro{[1-(2-pyridyl-κN)ethylidene]hydrazine-κN}copper(II))

✍ Tomyn, Stefaniya V. ;Gumienna-Kontecka, Elźbieta ;Fritsky, Igor O. ;Iskenderov, 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 235 KB

l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)

catena-Poly[[bis(pyridine-κN)iron(II)]-μ

catena-Poly[[bis(pyridine-κN)iron(II)]-μ-oxalato-κ2O,O′:κ2O′′,O′′′]

✍ Yao, Hua-Gang ;Ji, Min ;Ji, Sou-Hua ;An, Yong-Lin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 196 KB

The photodecomposition product μ-oxalato

The photodecomposition product μ-oxalato-1κ2O,O′:2κ2O′′,O′′′-bis{bis[2-(2-pyridyl)phenyl-κ2C,N]iridium(III)}–acetone (1/1.974)

✍ DeRosa, Maria C. ;Enright, Gary D. ;Evans, Christopher E. B. ;Crutchley, Robert 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 158 KB

The photodecomposition product l-oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis{bis[2-(2-pyridyl)phenylj 2 C,N]iridium(III)}-acetone (1/1.974