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(Bipyridyl-κ2N,N′)bis(η5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato-κO)cerium(III)

✍ Scribed by Kazhdan, Daniel ;Chomitz, Wayne A. ;Harman, William H. ;Hoette, Trisha M. ;Park, Cheol-Hwan

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 481 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807022209

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✦ Synopsis

The title compound, [Ce(CF 3 SO 3 )(C 10 H 15 ) 2 (C 10 H 8 N 2 )], crystallizes as a bent metallocene with an inner-sphere trifluoromethanesulfonate ligand [Cg1-Ce-Cg2 = 138.91 (1) A ˚; Cg1 and Cg2 are the centroids of the cyclopentadienyl rings]. The pentamethylcyclopentadienyl rings have a slightly staggered conformation. The bipyridine ligand has an N-C-C-N torsion angle of À8.2 (7) .

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