(2,2-Bipyridyl N,N′-dioxide-κ2O,O′)trichloridobis(methanol-κO)terbium(III)
✍ Scribed by Liu, Yin-Qiu ;Zeng, Xi-Rui ;Lei, Liang-Ping
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 733 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [TbCl~3~(C~10~H~12~N~2~O~2~)(CH~4~O)~2~], each Tb^III^ ion is seven-coordinate in a pentagonal-bipyramidal coordination geometry. A crystallographic twofold rotation axis passes through Tb and one Cl atom.
📜 SIMILAR VOLUMES
Bis(benzoato-j 2 O,O 0 0 0 )(2,2 0 0 0 -bipyridyl-j 2 N,N 0 0 0 )zinc(II)
Single-crystal X-ray study T = 130 K Mean '(C±C) = 0.005 A Ê R factor = 0.029 wR factor = 0.067 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu~2~(C~13~H~18~N~2~O~2~)~2~(ClO~4~)~2~(CH~4~O)], consists of two six-coordinate Jahn–Teller-distorted copper(II) complex units with the tetradentate ligand 2-{1-[2-(2-hydroxyethylamino)ethylimino]propyl}phenolate observed in a planar coordination mode. Each copper center has oc
In the title compound, (C~4~H~7~N~2~)~2~[Mn(C~7~H~4~O~3~)~2~(C~4~H~6~N~2~)~2~] [Mn(C~7~H~4~O~3~)~2~(CH~4~O)~2~]·2CH~4~O, there are two independent Mn^III^ ions, each located on an inversion center. The two Mn^III^ ions assume a distorted octahedral geometry and the complex anions are hydrogen bonded