2,2′-Bipyridyl-2-ium aqua(2,2′-bipyridyl-κ2N,N′)tetakis(nitrato-κ2O,O′)praseodymium(III) 2,2′-bipyridyl hemisolvate
✍ Scribed by Charushnikova, Iraida A. ;Den Auwer, Christophe
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 374 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 130 K Mean '(C±C) = 0.005 A Ê R factor = 0.029 wR factor = 0.067 Data-to-parameter ratio = 12.7
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the title complex, [TbCl~3~(C~10~H~12~N~2~O~2~)(CH~4~O)~2~], each Tb^III^ ion is seven-coordinate in a pentagonal-bipyramidal coordination geometry. A crystallographic twofold rotation axis passes through Tb and one Cl atom.
Bis(benzoato-j 2 O,O 0 0 0 )(2,2 0 0 0 -bipyridyl-j 2 N,N 0 0 0 )zinc(II)
In the molecular title complex, [Ag(C~4~H~4~NO~2~)(C~10~H~8~N~2~)], the Ag atom adopts a distorted T-shaped AgN~3~ coordination. Aromatic π–π stacking interactions [centroid–centroid separation = 3.8393 (17) Å] lead to centrosymmetric dimers of molecules in the crystal structure.