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Bis(acetonitrile-κN)(η5-pentamethylcyclopentadienyl)(pyrimidine-κN)rhodium(III) bis(hexafluoridophosphate)

✍ Scribed by Boyer, Julie L. ;Wilson, Scott R. ;Rauchfuss, Thomas B.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 983 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807044716

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✦ Synopsis

The title compound, [Rh(C 10 H 15

, where Cp* is pentamethylcyclopentadienyl, was obtained from the treatment of an acetonitrile solution of [Cp*Rh(NCMe) 3 ](PF 6 ) 2 with an excess of pyrimidine. The Rh III center is coordinated by one Cp* ring, two acetonitrile ligands and one pyrimidine ligand in a pseudo-octahedral geometry. Both PF 6 anions are disordered (site occupancies ca 0.4:0.6, and 0.3:0.4:0.3).

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