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Zeeman splittings of the two lowest excited states of [Ru(bpy)3](PF6)2

✍ Scribed by Dieter Braun; Erich Gallhuber; Hartmut Yersin

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 483 KB
Volume: 171
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)80061-h

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✦ Synopsis

For [Ru(bpy),] (PF,),, the splittings of the two lowest excited electronic states could be measured under magnetic fields (Zeeman effect ). The splittings of both states increase with the magnetic-field strength to 3 k 0.5 cm-' at B= 6 T. It is concluded that at B equal zero, the parent terms of these two states cannot be classified as originating from a situation in which one electron is localized on one ligand.

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