For [Ru(bpy),] (PF,),, the splittings of the two lowest excited electronic states could be measured under magnetic fields (Zeeman effect ). The splittings of both states increase with the magnetic-field strength to 3 k 0.5 cm-' at B= 6 T. It is concluded that at B equal zero, the parent terms of the
Geometrical distortions in excited A′2 states of single-crystal [Ru(bpy)3](PF6)2
✍ Scribed by T. Schönherr; J. Degen; E. Gallhuber; G. Hensler; H. Yersin
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 521 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0009-2614
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The last sentence of the second paragraph on page 125 (right column) is incorrect and misleading. It should read: Consequently, also these experimental results are at variance with the assumed electron localization but are explainable by a delocalized model with one chromophore exhibiting two low-l