For [Ru(bpy),] (PF,),, the splittings of the two lowest excited electronic states could be measured under magnetic fields (Zeeman effect ). The splittings of both states increase with the magnetic-field strength to 3 k 0.5 cm-' at B= 6 T. It is concluded that at B equal zero, the parent terms of the
Zeeman splittings of the two lowest excited states of [Ru(bpy)3](PF6)2: Chem. Phys. Letters 171 (1990) 122
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 26 KB
- Volume
- 173
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The last sentence of the second paragraph on page 125 (right column) is incorrect and misleading. It should read:
Consequently, also these experimental results are at variance with the assumed electron localization but are explainable by a delocalized model with one chromophore exhibiting two low-lying doubly degenerate excited states at B=O T.
๐ SIMILAR VOLUMES
The positions and intensities of the electronic origins in [Zn(bpy),] ( C104)\*: Ru( II) are strongly dependent on the orientation of an applied magnetic field within the metal-ligand plane. Spectra can be calculated by a mode1 in which the lowest-energy charge-transfer excitations involve an indivi