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Orientational dependences of the Zeeman effect in the lowest-excited states of [Zn(bpy)3](ClO4)2:Ru(II) and [Ru(bpy)3](PF6)2

โœ Scribed by H. Riesen; E. Krausz

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
467 KB
Volume
217
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The positions and intensities of the electronic origins in [Zn(bpy),] ( C104)*: Ru( II) are strongly dependent on the orientation of an applied magnetic field within the metal-ligand plane. Spectra can be calculated by a mode1 in which the lowest-energy charge-transfer excitations involve an individual metal-l&and subunit. The mode1 can also reproduce all the significant features of the spectra reported for [ Ru (bpy ) s ] (PF, ) *.

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