The positions and intensities of the electronic origins in [Zn(bpy),] ( C104)\*: Ru( II) are strongly dependent on the orientation of an applied magnetic field within the metal-ligand plane. Spectra can be calculated by a mode1 in which the lowest-energy charge-transfer excitations involve an indivi
Stark effects in the lowest-excited 3MLCT states of [Ru(bpy)(bpy-d8)2]2+ in [Zn(bpy)3](ClO4)2 (bpy = 2,2′-bipyridine)
✍ Scribed by Hans Riesen; Elmars Krausz
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 373 KB
- Volume
- 260
- Category
- Article
- ISSN
- 0009-2614
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The rate of 3MLCT excitation energy transfer between the two crystallographically equivalent metal-ligand subunits of [Ru(bpy)3] 2+ in the [Zn(bpy)3] (C104)2 lattice has been directly measured by time-resolved luminescence line-narrowing experiments. At 1.8 K the transfer rate is ~ I X l0 s s -1 in
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