Localised3MLCT states of [Ru(bpy)3−x(phen)x]2+ (x=0 to 3) in racemic [Zn(bpy)3] (ClO4)2
✍ Scribed by Hans Riesen; Lynne Wallace; Elmars Krausz
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 284 KB
- Volume
- 228
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Luminescence decay kinetics of the title series, measured after quasi-steady-state excitation, are found to be first order under all conditions. The decay rates of the X= 1 and 2 partially deuterated complexes are approximately evenly spaced between the x=0 and X= 3 values. Luminescence profiles are
The positions and intensities of the electronic origins in [Zn(bpy),] ( C104)\*: Ru( II) are strongly dependent on the orientation of an applied magnetic field within the metal-ligand plane. Spectra can be calculated by a mode1 in which the lowest-energy charge-transfer excitations involve an indivi
## Luminescence and excitation measurements were performed on single crystals of specifically deuterated compounds Ru( bpy-d,) ,(bpy) 3\_ ,( PF,) 2 (x= l-3) in the region of the sharp zero-phonon transitions at 4.2 and 2.1 K. The results are compared with the spectroscopic properties of the non-de