Vibration to vibration and rotation (WR) exchange occurs between CO and D, over the temperature range 340 K to 230 K, whilst at lower temperatures VT deactivation is dominant. Probabilities for these processes and for D, -D, deactivation are presented.
Vibrational deactivation of CO by n-H2, by p-H2 and by HD measured down to 77 K using laser fluorescence
โ Scribed by A.J. Andrews; C.J.S.M. Simpson
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 420 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Probabilities for the (VT) and (VR) deactivation of CO have been calculated from relaxation times measured down to 77 K using laser fluorescence. Only in the case of deactivation by p-H2 is the (VR) process important; its rate exceeds that for (VT) deactivation between 320 K and 110 K.
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