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Vibrational deactivation of CO by n-D2 and o-D2 measured between 340 K and 110 K using laser fluorescence

โœ Scribed by C.J.S.M. Simpson; A.J. Andrews; T.J. Price


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
336 KB
Volume
42
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Vibration to vibration and rotation (WR) exchange occurs between CO and D, over the temperature range 340 K to 230 K, whilst at lower temperatures VT deactivation is dominant. Probabilities for these processes and for D, -D, deactivation are presented.


๐Ÿ“œ SIMILAR VOLUMES


Vibrational deactivation of CO by n-H2,
โœ A.J. Andrews; C.J.S.M. Simpson ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 420 KB

Probabilities for the (VT) and (VR) deactivation of CO have been calculated from relaxation times measured down to 77 K using laser fluorescence. Only in the case of deactivation by p-H2 is the (VR) process important; its rate exceeds that for (VT) deactivation between 320 K and 110 K.

A photoacoustic study of the collisional
โœ J. Taine; F. Lepoutre; G. Louis ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 483 KB

A photoacoustic method is used under such experimental conditions that the (01'0) level ofC02 gas is not in e@li%rinrn with the other vibrational Ievck The rate mnsta.ntsk;o characterizing the CO2 (01'0) collisional deactivation by Nz, CO aad 02 are measured directly.

The measurement of rate constants for th
โœ G.J. Wilson; M.L. Turnidge; A.S. Solodukhin; C.J.S.M. Simpson ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 419 KB

Rate constants for the vibrational deactivation of 12C1b by Hz, Dz and 'He have been determined by laser-induced fluorescence in the gas phase at low temperatures. The rate constants for 12C160( u= 1 )-H2 and '\*C?O( u= 1 )-D2 have been measured down to 35 K and those for '\*C%(o= 1 )-'He have been