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Vibrational relaxation of CO by H2 down to 73 K using a chemical CO laser

✍ Scribed by A.J. Andrews; C.J.S.M. Simpson


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
333 KB
Volume
36
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


Vibrational deactivation of CO by n-H2,
✍ A.J. Andrews; C.J.S.M. Simpson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 420 KB

Probabilities for the (VT) and (VR) deactivation of CO have been calculated from relaxation times measured down to 77 K using laser fluorescence. Only in the case of deactivation by p-H2 is the (VR) process important; its rate exceeds that for (VT) deactivation between 320 K and 110 K.

Vibrational deactivation of CO by n-D2 a
✍ C.J.S.M. Simpson; A.J. Andrews; T.J. Price πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 336 KB

Vibration to vibration and rotation (WR) exchange occurs between CO and D, over the temperature range 340 K to 230 K, whilst at lower temperatures VT deactivation is dominant. Probabilities for these processes and for D, -D, deactivation are presented.