In the title compound, [Cd(C 24 H 27 N 7 )](ClO 4 ) 2 , the Cd 2+ ion is coordinated by six N atoms from the tripodal organic ligand in the form of a trigonal antiprism.
{Tris[2-(2-pyridylmethyleneimino)ethyl]amine}manganese(II) bis(perchlorate)
✍ Scribed by Li, Shu-Ni ;Ren, Yan-Wei ;Li, Jun ;Zhang, Feng-Xing ;Hu, Man-Cheng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 131 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Mn(C 24 H 27 N 7 )](ClO 4 ) 2 , the Mn II ion is chelated by a tris [2-(2-pyridylmethyleneimino)ethyl]amine ligand, in a distorted octahedral coordination geometry. Weak C-HÁ Á ÁO interactions occur between the perchlorate anions and the Mn II complex cation. metal-organic papers Acta Cryst. (2006). E62, m498-m499 Li et al. [Mn(C 24 H 27 N 7 )](ClO 4 ) 2 m499
📜 SIMILAR VOLUMES
The title compound, [Mn(C 31 H 31 N 7 )](ClO 4 ) 2 .0.435H 2 O, contains a high-spin Mn II atom which is coordinated by seven N atoms at the corners of a distorted pentagonal bipyramid.
In the title compound, [Ca(C 24 H 27 N 7 )(CH 3 OH)](ClO 4 ) 2 Á-CH 3 OH, the Ca 2+ ion is coordinated by all seven N atoms from the tris[2-(2-pyridylmethyleneamino)ethyl]amine ligand and by the O atom of a methanol molecule, in an approximately square-antiprismatic geometry.
Yellow crystals of the title compound, [Mn(dien) 2 ][Sb 4 S 7 ]Á-0.5H 2 O (dien = diethylenetriamine = C 4 H 13 N 3 ) were synthesized under solvothermal conditions by reacting MnSb 2 S 4 with pure dien. The Mn 2+ ion is in an octahedral environment of six N atoms of the tridentate dien molecules. T