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Methanol{tris­[2-(2-pyridylmethyl­eneamino)ethyl]amino-κ7N}calcium(II) bis­(perchlorate) methanol solvate

✍ Scribed by He, Hong-Shan


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
200 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Ca(C 24 H 27 N 7 )(CH 3 OH)](ClO 4 ) 2 Á-CH 3 OH, the Ca 2+ ion is coordinated by all seven N atoms from the tris[2-(2-pyridylmethyleneamino)ethyl]amine ligand and by the O atom of a methanol molecule, in an approximately square-antiprismatic geometry.


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✍ Lee, Rae Eun ;Park, Yeon Do ;Jeong, Jong Hwa 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 645 KB

In the title compound, [ZnCl~2~(C~14~H~23~N~5~)]·CH~3~OH, the Zn atom is coordinated by two N atoms and two Cl atoms in an approximately tetrahedral arrangement. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.69 (5)°. The methanol solvent molecule takes part in the formation of the