In the title compound, [Cd(C 24 H 27 N 7 )](ClO 4 ) 2 , the Cd 2+ ion is coordinated by six N atoms from the tripodal organic ligand in the form of a trigonal antiprism.
Methanol{tris[2-(2-pyridylmethyleneamino)ethyl]amino-κ7N}calcium(II) bis(perchlorate) methanol solvate
✍ Scribed by He, Hong-Shan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 200 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ca(C 24 H 27 N 7 )(CH 3 OH)](ClO 4 ) 2 Á-CH 3 OH, the Ca 2+ ion is coordinated by all seven N atoms from the tris[2-(2-pyridylmethyleneamino)ethyl]amine ligand and by the O atom of a methanol molecule, in an approximately square-antiprismatic geometry.
📜 SIMILAR VOLUMES
Bis{2-[tris(hydroxymethyl)methyliminomethyl]phenolato-3 N,O,O'}nickel(II) methanol solvate
In the title compound, [ZnCl~2~(C~14~H~23~N~5~)]·CH~3~OH, the Zn atom is coordinated by two N atoms and two Cl atoms in an approximately tetrahedral arrangement. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.69 (5)°. The methanol solvent molecule takes part in the formation of the
Diaminopropane-j 2 N,N 0 0 0 )[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) bis(perchlorate)