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{Bis[2-(3,5-dimethylpyrazol-1-yl)ethyl]amine-κ2N,N′}dichloridozinc(II) methanol solvate

✍ Scribed by Lee, Rae Eun ;Park, Yeon Do ;Jeong, Jong Hwa


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
645 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [ZnCl~2~(C~14~H~23~N~5~)]·CH~3~OH, the Zn atom is coordinated by two N atoms and two Cl atoms in an approximately tetrahedral arrangement. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.69 (5)°. The methanol solvent molecule takes part in the formation of the hydrogen-bond system.


📜 SIMILAR VOLUMES


Bis[2-(1H-imidazol-2-yl)phenolato-κ2N,O]
✍ He, Hong-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

In the title complex, [Zn(C 18 H 14 N 4 O 2 )]ÁCH 3 OH, two anionic 2-(1H-imidazol-2-yl)phenolate bidentate ligands coordinate through the phenolate O and imidazolyl N atoms to the central Zn II atom to give a four-coordinate tetrahedral geometry.

(Barbiturato-κO)[hydridotris(5-methyl-3-
✍ He, Hongshan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 357 KB

In the title compound, [Zn(C~30~H~28~BN~6~)(C~4~H~3~N~2~O~3~)]·CH~3~OH, the Zn^II^ atom is coordinated in a tetrahedral geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by one O atom from a barbiturate anion.