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{Tris[2-(2-pyridylmethyl­eneamino-κ2N,N′)eth­yl]­amine}­cadmium(II) bis­(perchlorate)

✍ Scribed by He, Hong-Shan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
206 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cd(C 24 H 27 N 7 )](ClO 4 ) 2 , the Cd 2+ ion is coordinated by six N atoms from the tripodal organic ligand in the form of a trigonal antiprism.

📜 SIMILAR VOLUMES

{Tris[2-(2-pyridylmethyl­eneimino)eth­yl
{Tris[2-(2-pyridylmethyl­eneimino)eth­yl]amine}manganese(II) bis(perchlorate)
✍ Li, Shu-Ni ;Ren, Yan-Wei ;Li, Jun ;Zhang, Feng-Xing ;Hu, Man-Cheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

In the title complex, [Mn(C 24 H 27 N 7 )](ClO 4 ) 2 , the Mn II ion is chelated by a tris [2-(2-pyridylmethyleneimino)ethyl]amine ligand, in a distorted octahedral coordination geometry. Weak C-HÁ Á ÁO interactions occur between the perchlorate anions and the Mn II complex cation. metal-organic pap

Methanol{tris­[2-(2-pyridylmethyl­eneami
Methanol{tris­[2-(2-pyridylmethyl­eneamino)ethyl]amino-κ7N}calcium(II) bis­(perchlorate) methanol solvate
✍ He, Hong-Shan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 200 KB

In the title compound, [Ca(C 24 H 27 N 7 )(CH 3 OH)](ClO 4 ) 2 Á-CH 3 OH, the Ca 2+ ion is coordinated by all seven N atoms from the tris[2-(2-pyridylmethyleneamino)ethyl]amine ligand and by the O atom of a methanol molecule, in an approximately square-antiprismatic geometry.