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{2,6-Bis[bis­(2-pyridylmeth­yl)aminomethyl]­pyridine}manganese(II) bis­(perchlorate) 0.435-hydrate

✍ Scribed by Hazell, Alan ;Toftlund, Hans


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
155 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Mn(C 31 H 31 N 7 )](ClO 4 ) 2 .0.435H 2 O, contains a high-spin Mn II atom which is coordinated by seven N atoms at the corners of a distorted pentagonal bipyramid.


📜 SIMILAR VOLUMES


{Tris[2-(2-pyridylmethyl­eneimino)eth­yl
✍ Li, Shu-Ni ;Ren, Yan-Wei ;Li, Jun ;Zhang, Feng-Xing ;Hu, Man-Cheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

In the title complex, [Mn(C 24 H 27 N 7 )](ClO 4 ) 2 , the Mn II ion is chelated by a tris [2-(2-pyridylmethyleneimino)ethyl]amine ligand, in a distorted octahedral coordination geometry. Weak C-HÁ Á ÁO interactions occur between the perchlorate anions and the Mn II complex cation. metal-organic pap