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Triethyl [1-14C]phosphonoacetate from [14C]carbon dioxide

✍ Scribed by Michel Crevoisier; William J. Guilford; Robert M. Coates

Publisher
John Wiley and Sons
Year
1983
Tongue
French
Weight
237 KB
Volume
20
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Lithiation of diethyl methylphosphonate (1) with n‐butyllithium followed by carbonation with [^14^C]carbon dioxide and esterification with diazoethane afforded high specific activity triethyl [1‐^14^C]phosphonoacetate (4) in 62% yield.

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