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Tricarbonyl-1,10-phenanthroline(triphenylphosphine)molybdenum(0)

✍ Scribed by Muir, Kathleen J. ;McQuillan, Geoffrey P. ;Harrison, William T. A.

Book ID: 104491697
Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 967 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807043176

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✦ Synopsis

In the title compound, [Mo(CO) 3 (C 18 H 15 P)(C 12 H 8 N 2 )] or C 33 H 23 MoN 2 O 3 P, the carbonyl groups are attached to one face of the MoC 3 N 2 P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal structure, a short C-HÁ Á ÁO interaction (HÁ Á ÁO = 2.34 A ˚) may help to establish the packing.

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