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Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)

✍ Scribed by Muir, Kathleen J. ;McQuillan, Geoffrey P. ;Harrison, William T. A.


Book ID
104491685
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
878 KB
Volume
63
Category
Article
ISSN
1600-5368

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In the title compound, [Mo(CO) 3 (C 18 H 15 P)(C 12 H 8 N 2 )] or C 33 H 23 MoN 2 O 3 P, the carbonyl groups are attached to one face of the MoC 3 N 2 P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.003 A Ê R factor = 0.027 wR factor = 0.072 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.