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π-Norbornadiène-chrome(0)-tricarbonyl-triphénylphosphine

✍ Scribed by Declercq, J. P. ;Germain, G. ;Van Meerssche, M. ;Chawdhury, S. A.

Book ID
117859904
Publisher
International Union of Crystallography
Year
1975
Weight
266 KB
Volume
31
Category
Article
ISSN
0567-7408

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✍ Muir, Kathleen J. ;McQuillan, Geoffrey P. ;Harrison, William T. A. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 967 KB

In the title compound, [Mo(CO) 3 (C 18 H 15 P)(C 12 H 8 N 2 )] or C 33 H 23 MoN 2 O 3 P, the carbonyl groups are attached to one face of the MoC 3 N 2 P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal