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Tricarbonyl-2,2-bipyridyl(triphenylphosphine)molybdenum(0)

✍ Scribed by Muir, Kathleen J. ;McQuillan, Geoffrey P. ;Harrison, William T. A.


Book ID
104491696
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
1008 KB
Volume
63
Category
Article
ISSN
1600-5368

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(2,2′-Bipyridyl)tricarbonyl(di-2-pyridyl
✍ Muir, Kathleen J. ;McQuillan, Geoffrey P. ;Harrison, William T. A. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 421 KB

The previous structure report [Howie & McQuillan (1986). J. of the title compound, [Mo(C 10 H 8 N 2 )(C 10 H 9 N 3 )(CO) 3 ], has been corrected. In the present structure, the precision of the Mo-C and Mo-N bond distances for the fac-MoC 3 N 3 centre are significantly improved, and an N atom and a C

Tricarbonyl-1,10-phenanthroline(tripheny
✍ Muir, Kathleen J. ;McQuillan, Geoffrey P. ;Harrison, William T. A. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 967 KB

In the title compound, [Mo(CO) 3 (C 18 H 15 P)(C 12 H 8 N 2 )] or C 33 H 23 MoN 2 O 3 P, the carbonyl groups are attached to one face of the MoC 3 N 2 P octahedron. Slight differences in the Mo-C bond lengths may be interpreted in terms of back-bonding models of electronic structure. In the crystal