Triaquabis[bis(3,5-dimethyl-1,2,4-triazol-1-yl)methane-κN4]copper(II) bis(perchlorate)
✍ Scribed by Xiang, Qun ;Cheng, Yu ;Ling, Yun ;Zhang, Lei ;Shi, Li-Yi
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 228 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .
The crystal structure of the title compound, {[Cu(C 12 H 12 N 6 )]-ClO 4 } n , consists of a one-dimensional cationic copper(I) chain and uncoordinated ClO 4 À anions. In the cationic chain, the Cu I center, which lies on a crystallographic twofold rotation axis, is coordinated by two N atoms from t