Bis[3-ethyl-4-(4-methylphenyl)-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N,N′]copper(II) bis(perchlorate)
✍ Scribed by Wu, Pingfeng ;Wang, Zuoxiang ;Zhou, Bugao ;Huang, Liaocheng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 292 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .
📜 SIMILAR VOLUMES
In the title complex, [Mn(C 22 H 17 N 3 ) 2 ](ClO 4 ) 2 , the MnN 6 coordination geometry is distorted octahedral, involving the six N atoms of two 4 0 -(4-methylphenyl)-2,2 0 :6 0 ,2 00 -terpyridine (ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 (