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trans-Bis­[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]­bis­(nitrato-κO)copper(II)

✍ Scribed by García-Couceiro, Urko ;Castillo, Oscar ;Luque, Antonio ;Beobide, Garikoitz ;Román, Pascual

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
562 KB
Volume
60
Category
Article
ISSN
1600-5368

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Bis[3-ethyl-4-(4-methylphenyl)-5-(2-pyri
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In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .

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In the title centrosymmetric dinuclear iron(II) compound, [Fe 2 (C 12 H 8 N 5 ) 2 (NCS) 2 (CH 4 O) 2 ], the deprotonated 3,5-di-2pyridyl-1,2,4-triazole ligand uses a pair of N pyridyl /N triazolyl atoms to chelate one metal atom and the other pair of N pyridyl / N triazolyl atoms to chelate the othe