Bis(μ-1,2,4-triazole-κ2N1:N2)bis[diaqua(oxalato-κ2O,O′)copper(II)]
✍ Scribed by Castillo, Oscar ;García-Couceiro, Urko ;Luque, Antonio ;García-Terán, Juan P. ;Román, Pascual
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 639 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
l-Oxalato-j 4 O 1 ,O 2 :O 1 0 0 0 ,O 2 0 0 0 -bis{[N,N 0 0 0 -bis(pyridin-2-ylmethylene)propane-1,2-diamine-j 4 -N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]copper(II)} bis(perchlorate)
l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)
In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.