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trans-(Isothio­cyanato-κN)phenyl­bis(triphenyl­phosphine-κP)platinum(II)

✍ Scribed by Otto, Stefanus ;Roodt, Andreas


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
99 KB
Volume
61
Category
Article
ISSN
1600-5368

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The Pd atom in the title compound, __trans__-[PdCl~2~(C~6~H~15~N)(C~18~H~15~P)], is in an approximately square-planar environment, coordinated by one triethylamine, one triphenylphosphine and two __trans__ Cl ligands.

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In the title complex, [Cd(NCS) 2 (C 5 H 5 N) 4 ], the Cd II atom lies on a center of inversion. It is coordinated by four N atoms from four pyridines and two N atoms from two isothiocyanate ions and has a slightly distorted octahedral geometry.

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The title compound, [PtCl~2~(C~8~H~19~P)(C~18~H~15~P)]·0.5C~4~H~8~O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-__tert__-butyl-2-trimethylsilyltriphosphine. The ^31^P{^1^H} NMR spectrum of the reaction mixture shows the formation of the title comp