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trans-Bis­[ethane-1,2-diyl­bis­(di­phenyl­phosphane)-κ2P,P′]­bis­(thio­cyanato-κN)molybdenum(II) toluene solvate

✍ Scribed by Philippopoulos, Athanassios I. ;Ziemer, Burkhard ;Filippou, Alexander C.


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
261 KB
Volume
58
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES


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Single-crystal X-ray study T = 180 K Mean '(C±C) = 0.008 A Ê Disorder in solvent or counterion R factor = 0.036 wR factor = 0.084 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The crystal structure of the title compound, [Cu(C 2 H 3 S 2 )-(C 18 H 15 P) 2 ]Á1.5C 7 H 8 , is reported. The compound is monomeric with the copper metal atom assuming a distorted tetrahedral geometry.

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Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org

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Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.056 wR factor = 0.166 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.