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cis-Dichloro­(di-tert-butyl­phosphine-κP)(triphenyl­phosphine-κP)platinum(II) tetra­hydro­furan hemisolvate

✍ Scribed by Chojnacki, Jaroslaw ;Robaszkiewicz, Andrzej ;Matern, Eberhard ;Baum, Elke ;Pikies, Jerzy

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
150 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [PtCl~2~(C~8~H~19~P)(C~18~H~15~P)]·0.5C~4~H~8~O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-tert-butyl-2-trimethylsilyltriphosphine. The ^31^P{^1^H} NMR spectrum of the reaction mixture shows the formation of the title compound together with a significant amount of triphenylphosphine and 1,1,3,3-tetra-tert-butyltriphosphine.

📜 SIMILAR VOLUMES

Di-μ-iodido-bis[iodido(triphenylphosphin
Di-μ-iodido-bis[iodido(triphenylphosphine-κP)platinum(II)]
✍ Biswas, Achintesh Narayan ;Bagchi, Vivek ;Das, Purak ;Bandyopadhyay, Pinaki 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 901 KB

Each Pt atom in the dimeric iodide-bridged title compound, [Pt~2~I~4~(C~18~H~15~P)~2~], is tetracoordinated by a triphenylphosphine P and three I atoms in an approximately square-planar geometry. The __trans__ influence of triphenylphosphine is evident from the longer Pt—I bond length.