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trans-Dichloro­(triethyl­amine-κN)(triphenyl­phosphine-κP)palladium(II)

✍ Scribed by Harding, Phimphaka ;Harding, David J. ;Saithong, Saowanit ;Pakawatchai, Chaveng ;Youngme, Sujittra


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
160 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The Pd atom in the title compound, trans-[PdCl~2~(C~6~H~15~N)(C~18~H~15~P)], is in an approximately square-planar environment, coordinated by one triethylamine, one triphenylphosphine and two trans Cl ligands.


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cis-Dichloro­(di-tert-butyl­phosphine-κP
✍ Chojnacki, Jaroslaw ;Robaszkiewicz, Andrzej ;Matern, Eberhard ;Baum, Elke ;Pikie 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 150 KB

The title compound, [PtCl~2~(C~8~H~19~P)(C~18~H~15~P)]·0.5C~4~H~8~O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-__tert__-butyl-2-trimethylsilyltriphosphine. The ^31^P{^1^H} NMR spectrum of the reaction mixture shows the formation of the title comp