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Total Synthesis of ( R )-Dihydroactinidiolide and ( R )-Actinidiolide Using Asymmetric Catalytic Hetero-Diels−Alder Methodology

✍ Scribed by Yao, Sulan; Johannsen, Mogens; Hazell, Rita G.; Jørgensen, Karl Anker

Book ID
123622155
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
137 KB
Volume
63
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of (R)-Dihydroactinidiolide and (R)-Actinidiolide Using Asymmetric Catalytic Hetero-Diels—Alder Methodology.
✍ S. YAO; M. JOHANNSEN; R. G. HAZELL; K. A. JOERGENSEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Total Synthesis of (R)-Dihydroactinidiolide and (R)-Actinidiolide Using Asymmetric Catalytic Hetero-Diels-Alder Methodology. -Key steps in the synthesis of title compounds (V) and (VI) are regio-and stereoselective hetero-Diels-Alder reaction of the diene (I) and subsequent rearrangement to the lac