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Stereoselective Synthesis of (+)-Goniodiol, (+)-Goniotriol, (–)-Goniofupyrone, and (+)-Altholactone Using a Catalytic Asymmetric Hetero-Diels–Alder/Allylboration Approach

✍ Scribed by Annaïck Favre; François Carreaux; Michael Deligny; Bertrand Carboni


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
225 KB
Volume
2008
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Total Synthesis of
✍ S. YAO; M. JOHANNSEN; R. G. HAZELL; K. A. JOERGENSEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Total Synthesis of (R)-Dihydroactinidiolide and (R)-Actinidiolide Using Asymmetric Catalytic Hetero-Diels-Alder Methodology. -Key steps in the synthesis of title compounds (V) and (VI) are regio-and stereoselective hetero-Diels-Alder reaction of the diene (I) and subsequent rearrangement to the lac